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<br />elements generally were not exceeded at most <br />main-stem sites in the lower basin; however, <br />total-recoverable iron and selenium standards <br />were frequently exceeded. During storm events in <br />the lower basin, tributaries contributed substantial <br />amounts of trace elements to the Arkansas River. <br />Median concentrations of dissolved solids <br />in the Arkansas River increased from a minimum <br />of 62.5 milligrams per liter in the upper basin at <br />Granite to 3,825 milligrams per liter in the lower <br />basin near the State line. A transition from <br />igneous and metamorphic rock to sedimentary <br />rock, in addition to the concentrating effects of <br />the use and reuse of water for irrigation, caused <br />this downstream increase in dissolved-solids <br />concentrations. <br />Ammonia and nitrate concentrations <br />increased downstream but were low in compar- <br />ison to State and Federal standards. Median <br />ammonia concentrations in the Arkansas River <br />ranged from 0.0 I 0 to 0.145 milligram per liter; <br />median nitrate concentrations at main-stem sites <br />ranged from 0.020 to 2.4 milligrams per liter. <br />High concentrations of ammonia downstream <br />from John Martin Reservoir, particularly during <br />low-flow regimes, are indicative of anoxic condi- <br />tions in the reservoir. Median total-phosphorus <br />concentrations were relatively low in the upper <br />basin, but they exceeded the recommended <br />concentration for total-phosphorus in rivers <br />(0.10 milligram per liter) at three sites in the <br />lower basin. <br />Suspended-sediment concentrations in the <br />Arkansas River upstream from Pueblo Reservoir <br />were relatively low but increased downstream. <br />Suspended-sediment concentrations typically <br />were much larger during snowmelt runoff, owing <br />to tributary inflow and resuspension of fluvial <br />sediment. Suspended-sediment concentrations <br />increased substantially during periods of elevated <br />runoff; the largest measured concentration in the <br />upper basin occurred during stonn-runoff condi- <br />tions. In the lower basin, median concentrations <br />ranged from 19 milligrams per liter at Pueblo to <br />724 milligrams per liter at Catlin Dam. <br /> <br />INTRODUCTION <br /> <br />The Arkansas River drains about 25,400 mi2 <br />and flows nearly 400 mi in Colorado before reaching <br />the Colorado-Kansas border (fig. I). Streamflow in the <br />Arkansas River Basin primarily is derived from snow- <br />melt in the mountains that border the upper region of <br />the basin and, to a lesser extent, from summer thunder- <br />storms that occur primarily on the eastern plains. <br />Water uses in the Arkansas River Basin include agri- <br />cultural, commercial, domestic, industrial, livestock, <br />mining, and power production. Although the primary <br />water use in the basin is agricultural, many municipal- <br />ities within and outside the Arkansas River Basin have <br />become increasingly dependent on the river as a water <br />supply. Thus, quality of water in the Arkansas River <br />Basin has become an important consideration to a <br />multitude of water users in Colorado. <br />In 1990, the U.S. Geological Survey (USGS), <br />in cooperation with the Colorado Springs Utilities, <br />Water Resources Department; Pueblo Board of Water <br />Works; Southeastern Colorado Water Conservancy <br />District; Pueblo County, Department of Planning and <br />Development; city of Aurora, Department of Utilities; <br />SI. Charles Mesa Water District; Upper Arkansas Area <br />Council of Governments; Upper Arkansas Water <br />Conservancy District; city of Pueblo, Department of <br />Utilities; Pueblo West Metropolitan District; Fremont <br />Sanitation District; cities of Rocky Ford, Las Animas, <br />and Lamar; and the Bureau of Reclamation, began a <br />study to assess existing water-quality conditions in the <br />Arkansas River Basin. <br /> <br />Purpose and Scope <br /> <br />This report describes the spatial and temporal <br />variations in water-quality conditions in the Arkansas <br />River Basin between April 1990 and March 1993. The <br />primary focus of this report is the water quality of the <br />Arkansas River; however tributary data, when appro- <br />priate, were used to assess water-quality effects on the <br />main stem of the river. <br />An extensive streamflow and water-quality <br />monitoring network was established in April 1990. <br />Water-quality data collected at ] 9 main-stem, 16 tribu- <br />tary, and 2 mine-drainage sites were used to describe <br />the spatial and temporal variations in water quality in <br />the Arkansas River Basin between April 1990 and <br />March 1993 (table I). The Leadville Mine Drainage <br /> <br />2 Water-Quality Assessment of tha Arkansas River Sasln.. Southaa.tern Colorado, 199~3 <br />